и) C3H8 ---> C3H6 ---> СH2 = CH - CH3 ---> СH2 = CH - CH2Cl ---> СH3 - CH2 - CH2OH ---> СH3 - CH2 - COOH ---> СH3 - CH2 - COOK ---> C2H6
Ni,t
СH3 - CH2 - CH3 -------- > СH2 = CH - CH3
t=250C
2СH2 = CH - CH3 + Cl2 ---------> 2СH2 = CH - CH2Cl
Ni,t
СH2 = CH - CH2Cl + H2 ------ > СH3 - CH2 - CH2Cl
СH3 - CH2 - CH2Cl + NaOH ----- > СH3 - CH2 - CH2OH
Kt,t
СH3 - CH2 - CH2OH + O2 ----- > СH3 - CH2 - COOH + H2O
2СH3 - CH2 - COOH + 2K ------ > 2СH3 - CH2 - COOK + H2↑
t
СH3 - CH2 - COOK + KOH -------- > CH3 - CH3 + K2CO3
к) C6H6 ---> C6H5CH3 ---> C6H5COOH ---> C6H5COOCH3
AlCl3
C6H6 + CH3Cl ------------ > C6H5CH3 + HCl
K2MnO4
C6H5CH3 + [O] --------------- > C6H5COOH + H2O
H2SO4
C6H5COOH + CH3OH --------------> C6H5COOCH3 + H2O